Oxidative Depolymerization of Cellulolytic Enzyme Lignin over Silicotungvanadium Polyoxometalates
نویسندگان
چکیده
منابع مشابه
Polyoxometalates in Oxidative Delignification of Chemical Pulps: Effect on Lignin
Chemical pulps are produced by chemical delignification of lignocelluloses such as wood or annual non-woody plants. After pulping (e.g., kraft pulping), the remaining lignin is removed by bleaching to produce a high quality, bright paper. The goal of bleaching is to remove lignin from the pulp without a negative effect on the cellulose; for this reason, delignification should be performed in a ...
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Lignin is a recalcitrant and underexploited natural feedstock for aromatic commodity chemicals, and its degradation generally requires the use of high temperatures and harsh reaction conditions. Herein we present an ambient temperature one-pot process for the controlled oxidation and depolymerization of this potent resource. Harnessing the potential of electrocatalytic oxidation in conjugation ...
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This article reported a novel low-temperature process for aromatics production through lignin depolymerization catalyzed by 0.1 wt% Pd-zeolite Y catalyst prepared by a facile method. Under the same reactive condition, the as-prepared Pd-zeolite Y catalysts exhibited much higher catalytic efficiency than zeolite Y or commercial Pd/Al2O3–zeolite composites. The selectivity of the Pd-zeolite Y tow...
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Cellulolytic enzymes are synthesized by a large number of micro-organisms which include fungi, actinomycetes, gliding bacteria (myxobacteria) and true bacteria. However, only the fungi appear to excrete large amounts of cellulase enzymes in active form into culture media and not surprisingly these are the enzyme systems that have been most extensively studied. Bacterial cellulases are cell-wall...
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A (super)critical transfer: The consecutive hydrogenolysis and hydrogenation of the lignin model compound dihydrobenzofuran was studied in supercritical methanolic solutions using porous metal oxide catalysts. These catalysts promote H(2) production from methanol followed by hydrogenolysis of the ether linkages and reduction of the aromatic rings, leading principally to a mixture of cyclohexanols.
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ژورنال
عنوان ژورنال: Polymers
سال: 2019
ISSN: 2073-4360
DOI: 10.3390/polym11030564